
TY  - JOUR
A1  - McAdam, C. John 
A1  - Morgan, Joy L. 
A1  - Murray, R. Eva 
A1  - Robinson, Brian H. 
A1  - Simpson, Jim 
T1  - Synthesis and Fluorescence Properties of New Enaminenaphthalimides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2004
VL  - 57
IS  - 6
SP  - 525
EP  - 530
KW  - 
UR  - https://doi.org/10.1071/CH03285 
N2  - The first 4-enamine-N-methyl-1,8-naphthalimides (amine = piperidine, pyrrolidine, morpholine, Prn2NH, Pri2NH) are reported. The X-ray crystal structure of the piperidine derivative confirmed the E-stereochemistry and showed strong &#928;&#8211;&#928; stacking in the unit cell. The enamines are strongly fluorescent and quantum yields do not vary with the pKb of the amine. The solvent dependence of &#955; abs and &#955; flu is consistent with significant charge separation in the excited state. 
ER  -

