
%0 Journal Article
%A de, Bruin HJ 
%A Kairaitis, D 
%A Szego, L 
%T Solvent Extraction of Mono(salicylato)beryllium, and the pH Titration of the System Beryllium-Salicylic Acid
%J Australian Journal of Chemistry
%D 1962/06/01
%V 15
%N 2
%P 218-227
%K 
%R https://doi.org/10.1071/CH9620218
%U https://www.publish.csiro.au/paper/CH9620218 
%X It has been shown that a salicylatoberyllium complex can be extracted from aqueous solutions by aliphatic alcohols. The distribution ratio is a symmetrical function of the logarithm of the free ligand concentration and passes through a maximum value ; the stability constants of the mono- and bis(salicylato)beryllium complexes have been determined from the data for points of equal extraction. The values obtained in this way are &#946;1 = 4.1 x 1012 and &#946;2 = 4.3 x 1022, in an ionic strength of 0.15. They agree fairly well with those obtained by pH-titration procedures, which are &#946;1 = 6.1 x 1012 and &#946;2 =7 x 1022. 
