
TY  - JOUR
A1  - de, Bruin HJ 
A1  - Kairaitis, D 
A1  - Szego, L 
T1  - Solvent Extraction of Mono(salicylato)beryllium, and the pH Titration of the System Beryllium-Salicylic Acid
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1962
VL  - 15
IS  - 2
SP  - 218
EP  - 227
KW  - 
UR  - https://doi.org/10.1071/CH9620218 
N2  - It has been shown that a salicylatoberyllium complex can be extracted from aqueous solutions by aliphatic alcohols. The distribution ratio is a symmetrical function of the logarithm of the free ligand concentration and passes through a maximum value ; the stability constants of the mono- and bis(salicylato)beryllium complexes have been determined from the data for points of equal extraction. The values obtained in this way are &#946;1 = 4.1 x 1012 and &#946;2 = 4.3 x 1022, in an ionic strength of 0.15. They agree fairly well with those obtained by pH-titration procedures, which are &#946;1 = 6.1 x 1012 and &#946;2 =7 x 1022. 
ER  -

