
%0 Journal Article
%A Sutton, GJ 
%T Some Studies in Inorganic Complexes. XIII. Chromium(III) and Molybdenum(III) with 2-Aminomethylpyridine (2-Picolylamine)
%J Australian Journal of Chemistry
%D 1962/06/01
%V 15
%N 2
%P 232-234
%K 
%R https://doi.org/10.1071/CH9620232
%U https://www.publish.csiro.au/paper/CH9620232 
%X A study has been made of complexes of chromium(III) and molybdenum(III) with the chelating ligand 2-aminomethylpyridine (2-picolylamine). They are of the type Crpic33+, Crpic2(H2O)23+, and Mopic33+, in which pic is the ligand 2-picolylamine. Conductance measurements in methanol and nitromethane are in agreement with their structures as six-coordinate complexes. The magnetic moments were found to be in the vicinity of 3.7 B.M. in all oases, showing that the chromium(III) and manganese(III) atoms are spin-free. The following salts were prepared and studied : [Crpic3]2[SO4]3.3H2O, [Crpic3]Cl3.3H2O, [Crpic2(H2O)2]Br3, [Crpic2(H2O)2][ClO4]3, and [Mopic3][ClO4]3.3H2O. 
