
TY  - JOUR
A1  - Sutton, GJ 
T1  - Some Studies in Inorganic Complexes. XIII. Chromium(III) and Molybdenum(III) with 2-Aminomethylpyridine (2-Picolylamine)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1962
VL  - 15
IS  - 2
SP  - 232
EP  - 234
KW  - 
UR  - https://doi.org/10.1071/CH9620232 
N2  - A study has been made of complexes of chromium(III) and molybdenum(III) with the chelating ligand 2-aminomethylpyridine (2-picolylamine). They are of the type Crpic33+, Crpic2(H2O)23+, and Mopic33+, in which pic is the ligand 2-picolylamine. Conductance measurements in methanol and nitromethane are in agreement with their structures as six-coordinate complexes. The magnetic moments were found to be in the vicinity of 3.7 B.M. in all oases, showing that the chromium(III) and manganese(III) atoms are spin-free. The following salts were prepared and studied : [Crpic3]2[SO4]3.3H2O, [Crpic3]Cl3.3H2O, [Crpic2(H2O)2]Br3, [Crpic2(H2O)2][ClO4]3, and [Mopic3][ClO4]3.3H2O. 
ER  -

