
%0 Journal Article
%A Sargeson, AM 
%T The Rate of Racemization and Isomerization of the <I>cis</I>-Chloroaquobis(ethylenediamine) cobalt(III) Ion
%J Australian Journal of Chemistry
%D 1963/06/01
%V 16
%N 3
%P 352-355
%K 
%R https://doi.org/10.1071/CH9630352
%U https://www.publish.csiro.au/paper/CH9630352 
%X The rate of isomerization of the cis-chloroaquobis(ethylenediamine)cobalt(III) ion to the trans-isomer k30° = 2.7 x 10-3 min-1 has been shown to be the same as the rate of racemization k30° = 2.61 x 10-3 min-1. The activation energies and entropies for the reactions are AEa = 27 ± 1 kcal/mole, AS? = $2 e.u., and &#916;Ea = 26.7 ± 0.2 kcal/mole, AS? = +2.3 e.u. respectively. 
