
TY  - JOUR
A1  - Sargeson, AM 
T1  - The Rate of Racemization and Isomerization of the <I>cis</I>-Chloroaquobis(ethylenediamine) cobalt(III) Ion
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1963
VL  - 16
IS  - 3
SP  - 352
EP  - 355
KW  - 
UR  - https://doi.org/10.1071/CH9630352 
N2  - The rate of isomerization of the cis-chloroaquobis(ethylenediamine)cobalt(III) ion to the trans-isomer k30° = 2.7 x 10-3 min-1 has been shown to be the same as the rate of racemization k30° = 2.61 x 10-3 min-1. The activation energies and entropies for the reactions are AEa = 27 ± 1 kcal/mole, AS? = $2 e.u., and &#916;Ea = 26.7 ± 0.2 kcal/mole, AS? = +2.3 e.u. respectively. 
ER  -

