
TY  - JOUR
A1  - Mole, T 
T1  - Organo-Aluminium Compounds. II. Nucleophilic Displacement of Base from Triphenylaluminium Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1963
VL  - 16
IS  - 5
SP  - 801
EP  - 806
KW  - 
UR  - https://doi.org/10.1071/CH9630801 
N2  - Some complexes of triphenylaluminium with ethers, amines, and benzonitrile are described. Proton magnetic resonance spectrometry and ebulliometry have been used to study equilibria of the type:       Basex ? Ph3Al.Basey Ph3Al.Basex + Basey.   Such equilibria may be attained at measurably slow rates, and catalysis by added ether has been observed in the case, Basex = Basey = triethylamine. The favoured mechanism for displacement is analogous to the SN2 reaction at a saturated carbon atom. 
ER  -

