
%0 Journal Article
%A Buckingham, DA 
%A Dwyer, FP 
%A Goodwin, HA 
%A Sargeson, AM 
%T Mono- and Bis-(2,2'-bipyridine) and (1,10-phenanthroline) chelates of ruthenium and osaium. III. Mono chelates of bivalent, tervalent, and quadrivalent osmium
%J Australian Journal of Chemistry
%D 1964/03/01
%V 17
%N 3
%P 315-324
%K 
%R https://doi.org/10.1071/CH9640315
%U https://www.publish.csiro.au/paper/CH9640315 
%X Osmium complexes of the type (BH)[OsX4B], K[OsX4B], [OSX4B]0, [OsX3pyB]0, [OsX3H2OB]0, [OspysB]+/2+, [Ospy4B]2+/3+, [OsX3py3]0, [OsX2py4]0, [OsX2acaB]0, [Osaca2B]0/+, [OsX2glyB]0, [Osgly2B]+, and [OsBen2]2+ have been prepared, where B = 1,10-phenanthroline or 2,2'-bipyridine, py = pyridine, aca = acetylacetonate, gly = glycinate, en = ethylenediamine, and X = Cl or Br. They are generally inert to dissociation of their ligands and to disproportionation. The existence of the possible isomeric forms among the complexes is discussed. 
