
TY  - JOUR
A1  - Buckingham, DA 
A1  - Dwyer, FP 
A1  - Goodwin, HA 
A1  - Sargeson, AM 
T1  - Mono- and Bis-(2,2'-bipyridine) and (1,10-phenanthroline) chelates of ruthenium and osaium. III. Mono chelates of bivalent, tervalent, and quadrivalent osmium
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1964
VL  - 17
IS  - 3
SP  - 315
EP  - 324
KW  - 
UR  - https://doi.org/10.1071/CH9640315 
N2  - Osmium complexes of the type (BH)[OsX4B], K[OsX4B], [OSX4B]0, [OsX3pyB]0, [OsX3H2OB]0, [OspysB]+/2+, [Ospy4B]2+/3+, [OsX3py3]0, [OsX2py4]0, [OsX2acaB]0, [Osaca2B]0/+, [OsX2glyB]0, [Osgly2B]+, and [OsBen2]2+ have been prepared, where B = 1,10-phenanthroline or 2,2'-bipyridine, py = pyridine, aca = acetylacetonate, gly = glycinate, en = ethylenediamine, and X = Cl or Br. They are generally inert to dissociation of their ligands and to disproportionation. The existence of the possible isomeric forms among the complexes is discussed. 
ER  -

