
%0 Journal Article
%A Johnson, WD 
%A Riggs, NV 
%T Acetoxylation by aryliodoso acetates. III. Effects of structural changes in the reactants
%J Australian Journal of Chemistry
%D 1964/07/01
%V 17
%N 7
%P 787-793
%K 
%R https://doi.org/10.1071/CH9640787
%U https://www.publish.csiro.au/paper/CH9640787 
%X Definite increases in rate of reaction between aryliodoso acetates and N-arylacetamides occur when electron-releasing groups are introduced into the N-arylacetamide nucleus, the Arrhenius A and E parameters decreasing simultaneously; electron-attracting substituents cause the reverse effects. Small, erratic changes in rate and the Arrhenius parameters accompany substitution in the aryliodoso nucleus. N-Methylation of aceto-p-toluidide inhibits the reaction completely. Possible mechanisms are briefly discussed. 
