
TY  - JOUR
A1  - Johnson, WD 
A1  - Riggs, NV 
T1  - Acetoxylation by aryliodoso acetates. III. Effects of structural changes in the reactants
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1964
VL  - 17
IS  - 7
SP  - 787
EP  - 793
KW  - 
UR  - https://doi.org/10.1071/CH9640787 
N2  - Definite increases in rate of reaction between aryliodoso acetates and N-arylacetamides occur when electron-releasing groups are introduced into the N-arylacetamide nucleus, the Arrhenius A and E parameters decreasing simultaneously; electron-attracting substituents cause the reverse effects. Small, erratic changes in rate and the Arrhenius parameters accompany substitution in the aryliodoso nucleus. N-Methylation of aceto-p-toluidide inhibits the reaction completely. Possible mechanisms are briefly discussed. 
ER  -

