
TY  - JOUR
A1  - Brown, RD 
A1  - Pez, GP 
A1  - O'Dwyer, MF 
T1  - Infrared spectrum, potential constants, and structure of thio-thionyl fluoride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1965
VL  - 18
IS  - 5
SP  - 627
EP  - 635
KW  - 
UR  - https://doi.org/10.1071/CH9650627 
N2  - An investigation of the infrared spectrum of gaseous thio-thionyl fluoride (SSF2) results in the following assignment of fundamentals:      A': v1 760.5±0.2cm-1,    v2 718.5±0.2 cm-1,        v3 411.2±0.4cm-1,    v4 364.1±0.3 cm-1.      A&quot;: v5 692.3±0.8cm-1,    v6 337.6±0.4 cm-1. A normal coordinate vibrational analysis has been performed and a set of ten force constants evaluated. Some conclusions are given regarding the electronic structure of SSF2. Thermodynamic functions based on the usual assumptions have been calculated for SSF2. A set of potential constants has been evaluated for disulphur monoxide, SSO, using the available infrared data. 
ER  -

