
TY  - JOUR
A1  - Hall, JR 
A1  - Plowman, RA 
A1  - Preston, HS 
T1  - Coordination compounds of substituted 1,10-Phenanthrolines and related dipyridyls. VIII. Complexes of silver and 2,9-Dimethyl-1,10-phenanthroline
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1965
VL  - 18
IS  - 9
SP  - 1345
EP  - 1349
KW  - 
UR  - https://doi.org/10.1071/CH9651345 
N2  - Addition of 2,9-dimethyl-1,10-phenanthroline (dmp) in organic solvents to aqueous solutions of silver(1) salts yielded mono complexes represented by AgXdmp, where X = NO3, Cl, Br, I; 2X = SO4, and bis complexes Ag(dmp),Y, where Y = NO3, Cl04. Water of crystallization was present only in the sulphate. The mono complexes were empirically three-coordinate. Low solubility prevented the determination of molecular weights. Infrared spectra indicated that the polyatomic anions were covalently bound. The 1 : 1 electrolyte [Ag(dmp)(py)]ClO4 subsequently prepared seemed to be an example of three-coordination. The bis complexes were 1 : 1 electrolytes in nitrobenzene and were most likely tetrahedral. 
ER  -

