
%0 Journal Article
%A Pillai, MGK 
%A Ramaswamy, K 
%A Pichai, R 
%T Vibrational amplitudes for thionyl tetrafluoride and sulphur tetrafluoride
%J Australian Journal of Chemistry
%D 1965/10/01
%V 18
%N 10
%P 1575-1578
%K 
%R https://doi.org/10.1071/CH9651575
%U https://www.publish.csiro.au/paper/CH9651575 
%X The potential energy constants and vibrational mean amplitudes for thionyl tetrafluoride were calculated using the Urey-Bradley Force Field (UBFF) with a view to finding out the influence of the oxygen atom on the SF4 group. It was found that the axial S-F stretching force constant is smaller than the equatorial S-F stretching force constant, which is consistent with the variation in the bond length. The behaviour of the oxygen atom is found to be similar to the lone pair of electrons in sulphur tetrafluoride. The vibrational mean amplitudes calculated from spectroscopic data are in very good agreement with the electron diffraction data. The large root mean square amplitude of vibration for equatorial-equatorial non-bonded fluorine atoms (0.099 &#506;) in sulphur tetrafluoride indicates the possibility of incomplete inversion as pointed out by Chantry and Ewing. 
