
TY  - JOUR
A1  - Brown, DJ 
A1  - Lyall, JM 
T1  - Pyrimidine reactions. XI. Amination rates for two chlorodimethylprimidines without solvent
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1965
VL  - 18
IS  - 11
SP  - 1811
EP  - 1817
KW  - 
UR  - https://doi.org/10.1071/CH9651811 
N2  - Second-order rate constants, Arrhenius parameters, and isokinetic temperatures are presented for the reactions of 2-chloro-4,6-dimethylpyrimidine and 4-chloro-2,6-dimethylpyrimidine with some n-alkyl-, branched alkyl-, and dialkylamines in the absence of a solvent. The differences between these values and those available for the same reactions in a solvent are briefly discussed. An equation is derived for satisfactorily converting the apparent first-order rate constants previously reported by us into second-order rate constants. 
ER  -

