
%0 Journal Article
%A Bloom, H 
%A Tricklebank, SB 
%T Molten salt mixtures. X. The thermochemistry of the binary molten salt systems CdCl<sub>2</sub>+PbCl<sub>2</sub>, CdCl<sub>2</sub>+NaCl, CdCl<sub>2</sub>+KCI, PbCl<sub>2</sub>+NaCl, PbCl<sub>2</sub>-KCl, and CdI<sub>2</sub>+KI
%J Australian Journal of Chemistry
%D 1966/02/01
%V 19
%N 2
%P 187-196
%K 
%R https://doi.org/10.1071/CH9660187
%U https://www.publish.csiro.au/paper/CH9660187 
%X The enthalpy change on cooling molten and solid salts and their mixtures from temperatures as high as 850º down to 26.9º has been measured by means of a Bunsen-type fusion calorimeter. The enthalpy of formation of solid mixtures has also been measured using a water solution calorimeter. From the combined results, heats of mixing have been determined for the molten salt systems investigated. In each system, with the exception of CdCl2 + PbCl2, the process of mixing is exothermic and the relative magnitude of the results can be explained by the formation of complex ions in the systems CdC12 +NaCl, CdCl2 +KCl, PbCl2 +KCl, and CdI2 +KI. Complex ions have not been detected in the other systems. 
