
TY  - JOUR
A1  - Bloom, H 
A1  - Tricklebank, SB 
T1  - Molten salt mixtures. X. The thermochemistry of the binary molten salt systems CdCl<sub>2</sub>+PbCl<sub>2</sub>, CdCl<sub>2</sub>+NaCl, CdCl<sub>2</sub>+KCI, PbCl<sub>2</sub>+NaCl, PbCl<sub>2</sub>-KCl, and CdI<sub>2</sub>+KI
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1966
VL  - 19
IS  - 2
SP  - 187
EP  - 196
KW  - 
UR  - https://doi.org/10.1071/CH9660187 
N2  - The enthalpy change on cooling molten and solid salts and their mixtures from temperatures as high as 850º down to 26.9º has been measured by means of a Bunsen-type fusion calorimeter. The enthalpy of formation of solid mixtures has also been measured using a water solution calorimeter. From the combined results, heats of mixing have been determined for the molten salt systems investigated. In each system, with the exception of CdCl2 + PbCl2, the process of mixing is exothermic and the relative magnitude of the results can be explained by the formation of complex ions in the systems CdC12 +NaCl, CdCl2 +KCl, PbCl2 +KCl, and CdI2 +KI. Complex ions have not been detected in the other systems. 
ER  -

