
%0 Journal Article
%A Coates, GE 
%A Kowala, C 
%A Swan, JM 
%T Coordination compounds of Group IB metals. I. Triethylphosphine complexes of gold(I) mercaptides
%J Australian Journal of Chemistry
%D 1966/04/01
%V 19
%N 4
%P 539-545
%K 
%R https://doi.org/10.1071/CH9660539
%U https://www.publish.csiro.au/paper/CH9660539 
%X Various triethylphosphine coordinated gold(1) mercaptides of formula Et3PAuSR (R = Me, Et, Pr, Bu, Bu1, Ph, CH2Ph, &#946;-C10H7, and CH2CH(NH2)C02H), and related sulphur derivatives of formula Et3PAuY (Y = SCN, SC(S)Net2, SC(S)OEt, and SC(NH2)NH2+Br-) have been prepared. Under appropriate conditions, displacement of the sulphur group from the gold atom is observed, either by another sulphur nucleophile, e.g. Et3PAuSR + Et2NCSS- &#8594; Et3PAuSC(S)Net2 + RS-, or by a. nucleophile such as Cl-, Br-, I-, NO3-, or CN-. 
