
TY  - JOUR
A1  - Coates, GE 
A1  - Kowala, C 
A1  - Swan, JM 
T1  - Coordination compounds of Group IB metals. I. Triethylphosphine complexes of gold(I) mercaptides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1966
VL  - 19
IS  - 4
SP  - 539
EP  - 545
KW  - 
UR  - https://doi.org/10.1071/CH9660539 
N2  - Various triethylphosphine coordinated gold(1) mercaptides of formula Et3PAuSR (R = Me, Et, Pr, Bu, Bu1, Ph, CH2Ph, &#946;-C10H7, and CH2CH(NH2)C02H), and related sulphur derivatives of formula Et3PAuY (Y = SCN, SC(S)Net2, SC(S)OEt, and SC(NH2)NH2+Br-) have been prepared. Under appropriate conditions, displacement of the sulphur group from the gold atom is observed, either by another sulphur nucleophile, e.g. Et3PAuSR + Et2NCSS- &#8594; Et3PAuSC(S)Net2 + RS-, or by a. nucleophile such as Cl-, Br-, I-, NO3-, or CN-. 
ER  -

