
%0 Journal Article
%A Bloom, H 
%A Easteal, AJ 
%T Electrochemical studies of molten salt mixtures. I. The electromotive forces of concentration cells with transference containing the molten electrolytesystems PbBr<sub>2</sub> + CsBr, PbBr<sub>2</sub> + RbBr, and PbBr<sub>2</sub> + KBr
%J Australian Journal of Chemistry
%D 1966/09/01
%V 19
%N 9
%P 1577-1590
%K 
%R https://doi.org/10.1071/CH9661577
%U https://www.publish.csiro.au/paper/CH9661577 
%X The e.m.f.'s of concentration cells with transference (i.e. with liquid junction), containing the binary molten salt systems, PbBr2+CsBr, PbBr2+RbBr, and PbBr2+KBr, have been measured as functions of temperature and electrolyte composition. The cell e.m.f.'s have been found to vary with temperature and electrolyte composition in a discontinuous manner: graphs of cell e.m.f. against temperature are in general a number of intersecting straight lines, as are graphs of cell e.m.f. against the negative logarithm of the mole fraction of one component. 
