
TY  - JOUR
A1  - Graddon, DP 
A1  - Heng, KB 
A1  - Watton, EC 
T1  - Studies in the stereochemistry of zinc(II). IV. Complexes of zinc halides with heterocyclic bases
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1966
VL  - 19
IS  - 10
SP  - 1801
EP  - 1811
KW  - 
UR  - https://doi.org/10.1071/CH9661801 
N2  - Complexes of zinc halides with heterocyclic bases of the types ZnX2B2, ZnX2B3, and ZnX2B4 have been prepared, where X = Cl, Br, I, or NCS and B = pyridine, 4-methylpyridine, or 2-methylpyridine. Infrared spectra and isomorphous incorporation of cobalt(II) indicate that in the solid state these compounds are tetrahedral, 5-coordinate, and octahedral respectively. Molecular weights and conductivities in nitrobenzene solution show that the compounds ZnX2B3 and ZnX2B4 dissociate in solution to ZnX2B4 and free base. 
ER  -

