
TY  - JOUR
A1  - Bosnich, B 
A1  - Dwyer, FP 
A1  - Sargeson, AM 
T1  - The rate of exchange of propylenediaminetetraacetic acid with its cadmium complex
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1966
VL  - 19
IS  - 12
SP  - 2213
EP  - 2228
KW  - 
UR  - https://doi.org/10.1071/CH9662213 
N2  - The polarimetric rates of exchange between optically active propylene- diaminetetraacetic acid (PDTA) and its cadmium complex, and that between ethylenediaminetetraacetic acid (EDTA) and the cadmium propylenediaminetetraacetato complex, have been measured in the pH range 4.75-7.00. An analysis of the reaction kinetics indicates that the exchange, in either case, occurs simultaneously by a first-order and second-order process, and it is concluded that both bimolecular and unimolecular pathways are operative in the exchange process. 
ER  -

