
TY  - JOUR
A1  - Carman, RM 
A1  - Dennis, N 
T1  - Diterpenoids. XI. Manool trihydrochloride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1967
VL  - 20
IS  - 1
SP  - 163
EP  - 169
KW  - 
UR  - https://doi.org/10.1071/CH9670163 
N2  - The crystalline trichloro compound obtained from sclareol (I), manool (VI), and the manoyl oxides (IX, X) by addition of hydrogen chloride has the 8R,13,16-trichlorolabdane structure (XII). The compound is a 1 : 1 mixture of C13 epimers which are inseparable by normal means. However, addition of the trichloride to an equal amount of the antipodal mixture obtained from the enantiomeric manoyl oxide [(-)X] readily gave two separable racemates. 
ER  -

