
%0 Journal Article
%A Buckingham, DA 
%A Durham, L 
%A Sargeson, AM 
%T Conformations, configurations, and proton reactions of colbalt(III) complexes
%J Australian Journal of Chemistry
%D 1967/02/01
%V 20
%N 2
%P 257-280
%K 
%R https://doi.org/10.1071/CH9670257
%U https://www.publish.csiro.au/paper/CH9670257 
%X Proton magnetic resonance spectroscopy allows the cis and trans isomers of [CoX2 en2] complexes to be distinguished. Some information has been obtained concerning the rate of chelate conformational interchange for cobalt-ethylenediamine, propylenediamine, N-methylethylenediamine, and malonate rings. For [Co(amino acid)en2]2+ complexes the diastereoisomeric pairs can be differentiated and the relative rates of CH and NH proton exchange have been observed for a variety of chelate rings including cobalt-amino acid, acetylacetonato, ethylenediamine, and malonato. 
