
TY  - JOUR
A1  - Bell, TN 
A1  - Johnson, BB 
T1  - The reaction of free radicals with trichlorosilane
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1967
VL  - 20
IS  - 8
SP  - 1545
EP  - 1551
KW  - 
UR  - https://doi.org/10.1071/CH9671545 
N2  - Trifluoromethyl radicals generated from the photolysis of hexafluoroacetone abstract hydrogen atoms from trichlorosilane; the competitive abstraction of chlorine atoms does not occur under the experimental conditions. The rate of the abstraction                            CF3 + SiHCl3 &#8594; CF3N + SiCl3   has been measured in comparison with the known rate for the recombination of trifluoromethyl radicals, to yield a rate constant,                      k = 1012.13exp(-6850/RT) ml mole-1 sec-1   Methyl radicals similarly abstract hydrogen to yield methane. A quantitative study of this reaction proved impractical, due to complications using acetone as a radical source. 
ER  -

