
%0 Journal Article
%A Bottomley, GA 
%A Spurling, TH 
%T Measurement of the temperature variation of virial coefficients. III. The second virial coefficient of Carbon Disulphide, Methyl Chloride, Acetone, and Methanol, and certain of their binary mixtures
%J Australian Journal of Chemistry
%D 1967/09/01
%V 20
%N 9
%P 1789-1796
%K 
%R https://doi.org/10.1071/CH9671789
%U https://www.publish.csiro.au/paper/CH9671789 
%X Second virial coefficients have been determined for carbon disulphide, methyl chloride, acetone, and methanol over the temperature range of 50-150° with some additional results at lower temperatures. Similar work has been conducted on the selected mixtures methyl chloride-carbon disulphide, methyl chloride-acetone, acetone-carbon disulphide, and methyl chloride-argon. Methanol, exceptionally, shows very significant third virial contributions in the sub-atmospheric pressure range. A comparison is made with recent models pertaining to molecular interactions between unlike molecules possessing dipolar and quadrupolar contributions to the intermolecular forces. 
