
%0 Journal Article
%A Saxena, RS 
%A Jain, MC 
%A Mittal, ML 
%T Electrometric investigations of an acid-thiomolybdate system and the formation of polyanions
%J Australian Journal of Chemistry
%D 1968/01/01
%V 21
%N 1
%P 91-96
%K 
%R https://doi.org/10.1071/CH9680091
%U https://www.publish.csiro.au/paper/CH9680091 
%X The acidification of sodium thiomolybdate with progressive addition of HCl has been studied by pH and conductometric measurements, which have revealed the formation of three different polymerized species, viz. (MO4S15)6-, (MO2S7)2-, and (Mo4S13)2- at pH ranges 7.5-8.5, 4.2-5.3, and 2.8-3.3 respectively. It was observed that at higher hydrogen ion concentration (pH < 2.5), thiomolybdate decomposes into hydrated molybdenum trisulphide, MoS3,H2O. 
