
TY  - JOUR
A1  - Saxena, RS 
A1  - Jain, MC 
A1  - Mittal, ML 
T1  - Electrometric investigations of an acid-thiomolybdate system and the formation of polyanions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1968
VL  - 21
IS  - 1
SP  - 91
EP  - 96
KW  - 
UR  - https://doi.org/10.1071/CH9680091 
N2  - The acidification of sodium thiomolybdate with progressive addition of HCl has been studied by pH and conductometric measurements, which have revealed the formation of three different polymerized species, viz. (MO4S15)6-, (MO2S7)2-, and (Mo4S13)2- at pH ranges 7.5-8.5, 4.2-5.3, and 2.8-3.3 respectively. It was observed that at higher hydrogen ion concentration (pH < 2.5), thiomolybdate decomposes into hydrated molybdenum trisulphide, MoS3,H2O. 
ER  -

