
%0 Journal Article
%A O'Conner, MJ 
%A West, BO 
%T N-Substituted salicylaldimine complexes of chromium(III)
%J Australian Journal of Chemistry
%D 1968/02/01
%V 21
%N 2
%P 369-372
%K 
%R https://doi.org/10.1071/CH9680369
%U https://www.publish.csiro.au/paper/CH9680369 
%X Tris(salicylaldehydato)chromium(111) reacts readily with primary amines or ammonia to give complexes of the form Cr(sal-NR)3 where R = n-C3H9, i-C4H9, p-C6H4CH3, p-C6H4Br. The complexes are monomeric in benzene, and have magnetic moments in the range 3.77-3.81 B.M. at room temperature. Crystal field splitting energies have been obtained for the complexes from their spectra. Ethylenediamine reacts with the salicylaldehyde complex to give a cationic complex containing the tridentate ligand -0-C6H4-CH=NCH2CH2-NH2. 
