
%0 Journal Article
%A Duncan, JF 
%A Percival, HJ 
%T Modification of chemical properties of iron cyanides in solid solutions
%J Australian Journal of Chemistry
%D 1968/09/01
%V 21
%N 9
%P 2175-2188
%K 
%R https://doi.org/10.1071/CH9682175
%U https://www.publish.csiro.au/paper/CH9682175 
%X The ions [Fe(CN)64-, [Fe(CN)63-, and [Fe(CN)5NO]2- have been incorporated as solid solutions in alkali-halide host lattices. For the hexacyanides, the CN stretch frequency is split in a manner which can be explained from C2v or D2h symmetry of the point defects introduced in the solid solutions. There is evidence of reduced species formed from [Fe(CN)6]3- and [Fe(CN)5NO]2-. 
