
%0 Journal Article
%A Kitching, W 
%A Adcock, W 
%A Hegarty, BF 
%T Nuclear magnetic resonance of some fluoro-substituted phenyl and benzyl mercurials
%J Australian Journal of Chemistry
%D 1968/10/01
%V 21
%N 10
%P 2411-2416
%K 
%R https://doi.org/10.1071/CH9682411
%U https://www.publish.csiro.au/paper/CH9682411 
%X l9F and lH nuclear magnetic resonance data are reported for the para and meta fluoro-phenyl and -benzyl mercurials of types R2Hg and RHgX where X is a halide. The 19F data for the fluorophenyl mercurials provide no evidence for direct aryl-mercury conjugation, and mercuri substituents exert very feeble electronic effects. The shielding for the fluorobenzyl mercurials suggests a quite pronounced o-p electron donating effect for the metallomethyl group (NCH2-). Some 199Hg-lH spin coupling constants are derived from the proton spectra of the benzyl mercurials. 
