
TY  - JOUR
A1  - Angyal, SJ 
T1  - Conformational analysis in carbohydrate chemistry. I. Conformational free energies. The conformations and &#945; : &#946; ratios of aldopyranoses in aqueous solution
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1968
VL  - 21
IS  - 11
SP  - 2737
EP  - 2746
KW  - 
UR  - https://doi.org/10.1071/CH9682737 
N2  - The relative free energies of the aldopyranoses in aqueous solution have been calculated, taking non-bonded interaction energies and the anomeric effect into account. It is shown that the calculated free-energy values correctly predict the predominant conformation of the &#945;- and &#946;-pyranose forms of each aldose. The &#945;- to &#946;-pyranose ratios of the aldoses in aqueous solution, calculated from these values, are in reasonable agreement with those determined experimentally. 
ER  -

