
TY  - JOUR
A1  - Angyal, SJ 
A1  - Dawes, K 
T1  - Conformational analysis in carbohydrate chemistry. II. Equilibria between reducing sugars and their glycosidic anhydrides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1968
VL  - 21
IS  - 11
SP  - 2747
EP  - 2760
KW  - 
UR  - https://doi.org/10.1071/CH9682747 
N2  - The position of the equilibria between aldohexoses and 3-deoxyaldohexoses and their 1,6-anhydrides, and between heptuloses and their 2,7-anhydrides, has been determined by gas chromatography. The results are in good agreement with data calculated from conformational interaction energies. D-Talose gives equal amounts of the 1,6-anhydropyranose and the 1,6-anhydrofuranose. D-glycero-D-gulo-Heptose gives 66% of the 1,7- and only 9% of the 1,6-anhydride. 
ER  -

