
%0 Journal Article
%A Chiswell, B 
%A Lee, KW 
%T Metal complexes of tridentate hybrid ligands. I. Cobalt and nickel conlplexes of ligands containing the donor sequence As-N-O
%J Australian Journal of Chemistry
%D 1969/11/01
%V 22
%N 11
%P 2315-2320
%K 
%R https://doi.org/10.1071/CH9692315
%U https://www.publish.csiro.au/paper/CH9692315 
%X The interaction of the new tridentate ?hybrid? ligand, N-o- dimethylarsino-phenylsalicylaldimine (As-N-O), with cobalt(II) salts leads to the formation of cationic octahedral cobalt(III) complexes of the type [Co(As-N-O)2]+. No cobalt(II) complex entities containing the ligand could be isolated. With nickel(II) salts three types of octahedral complexes were obtained: (a) [Ni(As-N-O)2],H2O, (b) Ni(As-N- O)X,-xH2O (X = Cl, Br, or NCS), (c) [Ni2(As-N-O)3ClO4]. Electronic spectra, conductivity measurements, and magnetic data have been used to determine the structure of the complexes isolated. The ?hybrid? ligand appears to operate overall as a relatively weak field ligand. 
