
TY  - JOUR
A1  - Chiswell, B 
A1  - Lee, KW 
T1  - Metal complexes of tridentate hybrid ligands. I. Cobalt and nickel conlplexes of ligands containing the donor sequence As-N-O
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1969
VL  - 22
IS  - 11
SP  - 2315
EP  - 2320
KW  - 
UR  - https://doi.org/10.1071/CH9692315 
N2  - The interaction of the new tridentate ?hybrid? ligand, N-o- dimethylarsino-phenylsalicylaldimine (As-N-O), with cobalt(II) salts leads to the formation of cationic octahedral cobalt(III) complexes of the type [Co(As-N-O)2]+. No cobalt(II) complex entities containing the ligand could be isolated. With nickel(II) salts three types of octahedral complexes were obtained: (a) [Ni(As-N-O)2],H2O, (b) Ni(As-N- O)X,-xH2O (X = Cl, Br, or NCS), (c) [Ni2(As-N-O)3ClO4]. Electronic spectra, conductivity measurements, and magnetic data have been used to determine the structure of the complexes isolated. The ?hybrid? ligand appears to operate overall as a relatively weak field ligand. 
ER  -

