
TY  - JOUR
A1  - Fergusson, JE 
A1  - Hickford, JH 
T1  - Studies in the chemistry of technetium. Complexes of technetium-(II), -(III), and -(IV) with 1,2-bis(diphenylphosphino)ethane
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1970
VL  - 23
IS  - 3
SP  - 453
EP  - 461
KW  - 
UR  - https://doi.org/10.1071/CH9700453 
N2  - Complexes of bi-and ter-valent technetium have been prepared with the   diphosphine 1,2-bis(diphenylphosphino)ethane, viz. [Tc(diphos)2X2] and [Tc(di-phos)2Br2]Br where X = CL, Br. The complexes can be formulated as octahedral compounds and both magnetic and spectral evidence agree with this. The quadrivalent technetium compounds TcBr4, TcBr4(Ph3P)2, and the salts (diphos-H2)TcX6 (X = CL, Br) and Ag2TcCl6 have also been prepared and are described. Attempts to prepare the trichloride (TcCL3) are also reported. 
ER  -

