
TY  - JOUR
A1  - Coutts, RSP 
A1  - Wailes, PC 
A1  - Kingston, JV 
T1  - Xanthates of titanium(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1970
VL  - 23
IS  - 3
SP  - 469
EP  - 473
KW  - 
UR  - https://doi.org/10.1071/CH9700469 
N2  - The first xanthates of titanium have been prepared from cp2TiCl (cp = &#960;-cyclo-pentadienyl) and NaS2COR (R = CH3, C2H2, n-C3H7, n-C4H9, and n-C5H11) in air-free water under inert atmosphere. The trivalent titanium complexes are blue in colour, monomeric, and extremely sensitive to oxygen, with one unpaired electron per titanium atom. They are believed to be of the form    (See diagram in article)  with bidentate xanthato ligands, analogous to the corresponding dithiocarbamates. 
ER  -

