
%0 Journal Article
%A Chan, SC 
%A Cheung, TL 
%T Octahedral cobalt(III) complexes of the chloropentammine type. XX. The preparation, properties, and reactions of some chlorocycloalkylaminebis- (ethylenediamine)cobalt(III) salts
%J Australian Journal of Chemistry
%D 1970/04/01
%V 23
%N 4
%P 707-713
%K 
%R https://doi.org/10.1071/CH9700707
%U https://www.publish.csiro.au/paper/CH9700707 
%X Salts of one isomeric form of the chlorocycloalkylaminebis(ethylenediamine)cobalt(111) series of cations have been prepared and characterized. They are tentatively assigned a cis configuration on the basis of visible absorption spectroscopy. The first-order rate constants for the solvolytic aquation of these cations have been determined at 50.5º, and the results suggest the presence of steric acceleration. The second-order rate constants for the base hydrolysis of these cations have also been determined at 0º and ionic strength of 0.1M. These results are discussed in terms of the conjugate-base/ion-pair mechanistic spectrum postulated previously. 
