
%0 Journal Article
%A Casey, AT 
%A Ham, NS 
%A Mackey, DJ 
%A Martin, RL 
%T Synthesis and infrared spectra of some dithiocacodylate complexes
%J Australian Journal of Chemistry
%D 1970/06/01
%V 23
%N 6
%P 1117-1123
%K 
%R https://doi.org/10.1071/CH9701117
%U https://www.publish.csiro.au/paper/CH9701117 
%X The synthesis of dithiocacodylate complexes of the metals chromium(111), indium(111), manganese(11), cobalt(11), nicke1(11),  zinc(11), and copper(1) is described. The compounds can be prepared either from sodium dithiocacodylate Na[S2As(CH3)2] or by passing hydrogen sulphide through a methanolic solution of the metal cacodylate in the presence of hydrogen chloride. The infrared spectra in the region 4000-40 cm-1 of the new compounds have been recorded and assigned by a comparison with the spectra of several compounds which are closely related. The arsenic-sulphur and metal-sulphur stretching frequencies occur in the region of 450 cm-1 and 260-340 cm-1, respectively. 
