
TY  - JOUR
A1  - Casey, AT 
A1  - Ham, NS 
A1  - Mackey, DJ 
A1  - Martin, RL 
T1  - Synthesis and infrared spectra of some dithiocacodylate complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1970
VL  - 23
IS  - 6
SP  - 1117
EP  - 1123
KW  - 
UR  - https://doi.org/10.1071/CH9701117 
N2  - The synthesis of dithiocacodylate complexes of the metals chromium(111), indium(111), manganese(11), cobalt(11), nicke1(11),  zinc(11), and copper(1) is described. The compounds can be prepared either from sodium dithiocacodylate Na[S2As(CH3)2] or by passing hydrogen sulphide through a methanolic solution of the metal cacodylate in the presence of hydrogen chloride. The infrared spectra in the region 4000-40 cm-1 of the new compounds have been recorded and assigned by a comparison with the spectra of several compounds which are closely related. The arsenic-sulphur and metal-sulphur stretching frequencies occur in the region of 450 cm-1 and 260-340 cm-1, respectively. 
ER  -

