
%0 Journal Article
%A Heath, GA 
%A Martin, RL 
%T The synthesis and properties of tris(dithioacetylacetonato) complexes of iron(III), ruthenium(III), and osmium(III)
%J Australian Journal of Chemistry
%D 1970/09/01
%V 23
%N 9
%P 1721-1734
%K 
%R https://doi.org/10.1071/CH9701721
%U https://www.publish.csiro.au/paper/CH9701721 
%X The syntheses of the iron(111), ruthenium(111), and osmium(111) complexes of dithioacetylacetone are described. The tris chelates are neutral low-spin (S = 1/2)monomers. Polarography in acetone reveals a ready one-electron reduction for each complex. Infrared and e.s.r. spectra are reported. The magnetic susceptibilities have been measured as a function of temperature. The electronic absorption spectra are compared with those of the related cobalt(111) group complexes, and some tentative assignments of charge transfer bands are provided. 
