
TY  - JOUR
A1  - Heath, GA 
A1  - Martin, RL 
T1  - The synthesis and properties of tris(dithioacetylacetonato) complexes of iron(III), ruthenium(III), and osmium(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1970
VL  - 23
IS  - 9
SP  - 1721
EP  - 1734
KW  - 
UR  - https://doi.org/10.1071/CH9701721 
N2  - The syntheses of the iron(111), ruthenium(111), and osmium(111) complexes of dithioacetylacetone are described. The tris chelates are neutral low-spin (S = 1/2)monomers. Polarography in acetone reveals a ready one-electron reduction for each complex. Infrared and e.s.r. spectra are reported. The magnetic susceptibilities have been measured as a function of temperature. The electronic absorption spectra are compared with those of the related cobalt(111) group complexes, and some tentative assignments of charge transfer bands are provided. 
ER  -

