
TY  - JOUR
A1  - West, RJ 
A1  - Lincoln, SF 
T1  - The exchange of acetonitrile on iron(II) in acetonitrile solvent. A nitrogen-14 nuclear magnetic resonance study
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1971
VL  - 24
IS  - 6
SP  - 1169
EP  - 1175
KW  - 
UR  - https://doi.org/10.1071/CH9711169C 
N2  - A 14N n.m.r. study of the exchange reaction Fe(CH3CN)62+ &#9586; CH3CN in CH3CN solvent is reported. The value for k 1 (25&#176;C) from the rate law R = 6k1[Fe(CH3CN)62+] is (5.5 &#177; 0.8) &#215; 105 s-1, &#916;H&#8225; = 9.7 &#177; 0.7 kcal mol-1, &#916;S&#8225; = 0.3 &#177; 2.2 cal mol-1 K-1, and A/h = 5.0 &#215; 106 Hz. These data are compared with those of related systems. 
ER  -

