
%0 Journal Article
%A Johnson, CHJ 
%A Spurling, TH 
%T Pairwise additive third virial coefficients for multipolar molecules : Application to water vapour
%J Australian Journal of Chemistry
%D 1971/08/01
%V 24
%N 8
%P 1567-1580
%K 
%R https://doi.org/10.1071/CH9711567
%U https://www.publish.csiro.au/paper/CH9711567 
%X Pairwise additive third virial coefficients for axially symmetric multipolar molecules have been calculated using a non-product multidimensional integration formula. Results for the Stockmayer potential agree with the corrected results of Rowlinson. It is found that the inclusion of the dipole-quadrupole and quadrupole-quadrupole terms in the potential function has a marked qualitative effect on the shape of the C-T curve. Values of the third virial coefficient for water vapour calculated using a potential function derived from gaseous viscosity and second virial coefficient data are in good agreement with the experimental values. 
