
TY  - JOUR
A1  - Deacon, GB 
A1  - Parrott, JC 
T1  - Organoindium compounds. I. Preparative routes to pentafluorophenylindium compounds
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1971
VL  - 24
IS  - 9
SP  - 1771
EP  - 1779
KW  - 
UR  - https://doi.org/10.1071/CH9711771 
N2  - Trispentafluorophenylindium has been prepared by heating iodopentafluoro-benzene with an excess of indium metal, but was obtained mixed with iodobispenta-fluorophenylindium when the stoicheiometric amount was used. An attempted synthesis by thermal decomposition of indium trispentafluorobenzoate was un-successful. Reaction of indium with bispentafluorophenylmercury and subsequent treatment with ether gave (C6F5)3In,OEt2. The complex (C6F5)3In,diox (diox = 1,4-dioxan) has been obtained by reaction of indium trichloride with pentafluorophenyl-magnesium chloride or with an excess of bispentafluorophenylmagnesium, and C6F5InCl2,diox from bispentafluorophenylmagnesium and an excess of indium trichloride. 
ER  -

