
TY  - JOUR
A1  - Laver, JL 
A1  - Smith, PW 
T1  - Luminescence and photochemistry of transition metal complexes. I. Studies of temperature dependence of tervalent chromium complexes with oxygen-, nitrogen-, and carbon-coordinated ligands
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1971
VL  - 24
IS  - 9
SP  - 1807
EP  - 1815
KW  - 
UR  - https://doi.org/10.1071/CH9711807 
N2  - Experimental investigations of the luminescence exhibited by a range of tervalent chromium complexes are reported. The effects of the coordinated ligand on the temperature dependence of phosphorescence are examined and rationalized in terms of the 4T2-2E energy interval. In the case of hexaureachromium complexes which emit both phosphorescence and fluorescence the varying emission intensities observed for compounds with a variety of anions are interpreted in terms of competition between the non-radiative thermal repopulation process 2E ~~&#8594; 4T2 and the radiative processes 2E &#8594; 4A2, 4T2 &#8594; 4A2. 
ER  -

