
%0 Journal Article
%A Baker, JR 
%A Watson, ID 
%A Williamson, AG 
%T Hydrogen bonding in chloroform and ether mixtures
%J Australian Journal of Chemistry
%D 1971/10/01
%V 24
%N 10
%P 2047-2051
%K 
%R https://doi.org/10.1071/CH9712047
%U https://www.publish.csiro.au/paper/CH9712047 
%X The hydrogen bonding between chloroform and di-n-alkyl ethers has been studied over the temperature range -50°C to + 50°C using proton magnetic resonance. The measurements of chemical shift have been interpreted in terms of the formation of a 1 : 1 complex between the chloroform and the ether. Mole fraction association constants in the range 1-5 were found. The enthalpies of formation of the complexes deduced from the temperature coefficients of the equilibrium constants varied from -8 kJ mol-1 to -11.7 kJ mol-1. 
