
%0 Journal Article
%A Coutts, RSP 
%A Martin, RL 
%A Wailes, PC 
%T Monocyclopentadienyltitanium(III) compounds. I. Halides and their tetrahydrofuran complexes
%J Australian Journal of Chemistry
%D 1971/12/01
%V 24
%N 12
%P 2533-2540
%K 
%R https://doi.org/10.1071/CH9712533
%U https://www.publish.csiro.au/paper/CH9712533 
%X The halides of rnonocyclopentadienyItitanium(~~~) with the general formula cpTiXz (where X = C1, Br, and I ; and cp = T-cyclopentadienyl) have been prepared by pyrolysis from their tetrahydrofuran complexes (cpTiXz,THF). The THF com- plexes were prepared from the appropriate cyclopentadienyltitanium(~v) trihalide by reduction in THF. They are believed to be monomers of the form shown below, involving a pseudo-tetrahedral stereochemistry about the central titanium atom: 
