
TY  - JOUR
A1  - Cozens, RJ 
A1  - Murray, KS 
T1  - Mixed Schiff-base &#946;-diketone complexes of cobalt(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1972
VL  - 25
IS  - 5
SP  - 911
EP  - 917
KW  - 
UR  - https://doi.org/10.1071/CH9720911 
N2  - Mixed-ligand chelate complexes of cobalt(111) of the type (&#946;-diketone)Co(salen) have been synthesized using replacement reactions of the coba1t(111) species XCo(salen) (X = halogen, alkyl group; salen = tetradentate Schiff-base ligand) by the appropriate &#946;-diketone, or its sodium or thallium(1) salt. Studies of their infrared, N.M.R.,and mass spectra point to the formation of cis oxygen-bonded &#946;-diketone chelates, in which the salen group adopts an unusual twisted configuration. 
ER  -

